Dehalogenation - Wikipedia
In organic chemistry, dehalogenation is a set of chemical reactions that involve the cleavage of carbon - halogen bonds; as such, it is the inverse reaction of halogenation.
Dehalogenation - an overview | ScienceDirect Topics
Dehalogenation is the process of removing halogen atoms from compounds, such as halogenated dyes, which occurs during high-temperature vatting or dyeing, leading to a decrease in the …
Arene, alkene or alkane synthesis by dehalogenation or reductive …
Polymeric mechanoradicals, which can be generated by homolytic cleavage of the polymer chains by ball milling, offer a more convenient and safer alternative for radical chain initiation. The …
Enzymatic halogenation and dehalogenation reactions: pervasive …
This review details the scope and mechanism of nature’s halogenation and dehalogenation enzymatic strategies, highlights gaps in our understanding, and posits where new advances in …
Hydro- and deutero-dehalogenation reactions: An overview of …
Hydro-dehalogenation (HDH) and deuteron-dehalogenation (DDH) are crucial transformations in organic synthesis, enabling the removal of halogen atoms from organic molecules and their …
Dehalogenation of persistent halogenated organic compounds: A …
2015年7月1日 · Dehalogenation is one of the highly important degradation reactions for halogenated organic compounds (HOCs) in the environment, which is also being developed as …
Cobamide-mediated enzymatic reductive dehalogenation via …
2017年7月3日 · Here the authors proposed a catalytic mechanism for dehalogenation that relies on a long-range electron transfer from the cobalt in the centre of the enzyme’s cofactor to the …
Bacterial dehalogenases: biochemistry, genetics, and …
Concerning the enzymatic cleavage of the carbon-halogen bond, seven mechanisms of dehalogenation are known, namely, reductive, oxygenolytic, hydrolytic, and thiolytic …
II. Radical Formation by Dehalogenation - Chemistry LibreTexts
2022年9月13日 · Radical Formation by Dehalogenation is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Roger W. …
Reductive dehalogenase structure suggests a mechanism for B12 …
2014年10月19日 · In contrast to the carbon–cobalt bond chemistry catalysed by the other cobalamin-dependent subfamilies 13, we propose that reductive dehalogenases achieve …
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